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Print: ISSN 0914-4935
Online: ISSN 2435-0869
Sensors and Materials
is an international peer-reviewed open access journal to provide a forum for researchers working in multidisciplinary fields of sensing technology.
Online: ISSN 2435-0869
Sensors and Materials
is an international peer-reviewed open access journal to provide a forum for researchers working in multidisciplinary fields of sensing technology.
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Sensors and Materials
is covered by Science Citation Index Expanded (Clarivate Analytics), Scopus (Elsevier), and other databases.
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Sensors and Materials
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is covered by Science Citation Index Expanded (Clarivate Analytics), Scopus (Elsevier), and other databases.
Instructions to authors
English 日本語
Instructions for manuscript preparation
English 日本語
Template
English
Publisher
MYU K.K.
Sensors and Materials
1-23-3-303 Sendagi,
Bunkyo-ku, Tokyo 113-0022, Japan
Tel: 81-3-3827-8549
Fax: 81-3-3827-8547
MYU Research, a scientific publisher, seeks a native English-speaking proofreader with a scientific background. B.Sc. or higher degree is desirable. In-office position; work hours negotiable. Call 03-3827-8549 for further information.
MYU Research
(proofreading and recording)
MYU K.K.
(translation service)
The Art of Writing Scientific Papers
(How to write scientific papers)
(Japanese Only)
Sensors and Materials, Volume 19, Number 2 (2007)
Copyright(C) MYU K.K.
Copyright(C) MYU K.K.
|
pp. 123-132
S&M670 Research Paper Published: 2007 Luminescent Europium Chelates Synthesis and Fluorescence Properties [PDF] Quanguo He, Xueli Guo, Yongqiang Zhang, Yan Deng and Wei Wu (Received November 22, 2006; Accepted March 29, 2007) Keywords: 4,7-bis(sulfhydrylphenyl)-1,10-phenanthroline-2, 9-dicarboxylic acid (BSPDA), sulfhydrylization (thiolation), europium chelates, luminescence, time-resolved fluorescence, fluorescence lifetime
The europium(III)-chelating ligand BSPDA containing a thiolated group (BSPDA, an abbreviation of 4,7-bis(sulfhydrylphenyl)-1,10- phenanthroline-2,9-dicarboxylic acid) was synthesized from BCPDA (BCPDA, abbreviated form of 4,7-bis (chlorosulfophenyl)-1,10-phenanthroline-2,9-dicarboxylic acid) by reduction, and then complexed with europium (III, Eu3+) to give 1:1 and 2:1 complexes in molar ratio. The luminescent europium chelates’ fluorescence spectra and related lifetimes exceeding several hundreds of microseconds were determined, confirming that the 2:1 complexes have a slightly longer lifetime than the 1:1 complexes because of the more efficient complex interaction and energy transfer from the ligand BSPDA to europium(III) in the former. The results have significant implications to time-resolved-fluorescence-based nanostructuring and detection on biosensor surfaces.
Corresponding author: Yan Deng Cite this article Quanguo He, Xueli Guo, Yongqiang Zhang, Yan Deng and Wei Wu, Luminescent Europium Chelates Synthesis and Fluorescence Properties, Sens. Mater., Vol. 19, No. 2, 2007, p. 123-132. |
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