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Vol. 32, No. 8(2), S&M2292

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Sensors and Materials, Volume 31, Number 4(1) (2019)
Copyright(C) MYU K.K.
pp. 1191-1203
S&M1845 Research Paper of Special Issue
https://doi.org/10.18494/SAM.2019.2179
Published: April 11, 2019

Carbon-black-doped Polyimide-modified Glassy Carbon Electrode for Sensitive Nonenzymatic Amperometric Determination of Hydrogen Peroxide [PDF]

Yue Wang, Lin Chen, Yan Zhang, Qingnan Wang, Ruidan Ma, Yasushi Hasebe, Zhiqiang Zhang, and Zhizhi Hu

(Received November 2, 2018; Accepted December 3, 2018)

Keywords: polyimide, carbon black, hydrogen peroxide, sensor

In this study, a novel nonenzymatic sensor for the determination of hydrogen peroxide (H2O2) was developed. The direct electrocatalytic oxidation of H2O2 in an aqueous medium at a carbon-black (CB)-doped self-made polyimide (PI)-modified glassy carbon electrode (GCE) was investigated. The fabrication of this electrode is simple and reproducible. The filmlike surface was prepared by directly mixing the CB and PI solution. Under optimized conditions, the linear range of H2O2 is from 6 to 10000 µM with the detection limit of 1 µM. The electrode exhibited high stability, excellent sensitivity, stable reproducibility, and fast response time (less than 5 s). The results show that PI can be used as a reliable and long-life sensor for hydrogen peroxide detection, exhibiting a new application for the PI.

Corresponding author: Yasushi Hasebe, Zhizhi Hu


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Cite this article
Yue Wang, Lin Chen, Yan Zhang, Qingnan Wang, Ruidan Ma, Yasushi Hasebe, Zhiqiang Zhang, and Zhizhi Hu, Carbon-black-doped Polyimide-modified Glassy Carbon Electrode for Sensitive Nonenzymatic Amperometric Determination of Hydrogen Peroxide, Sens. Mater., Vol. 31, No. 4, 2019, p. 1191-1203.



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